Yury Kissin's Alkene Polymerization Reactions with Transition Metal PDF

By Yury Kissin

ISBN-10: 0444532153

ISBN-13: 9780444532152

ISBN-10: 1435628756

ISBN-13: 9781435628755

The e-book describes the most recent advertisement polymerization catalysts for the synthesis of polyethylenes and polypropyleneThe booklet offers a close description of the multi-center nature of industrial Ziegler-Natta catalysts.The booklet devotes really good chapters to crucial features of transition steel polymerization catalysts: the reactions resulting in the formation of lively facilities, the chemistry and stereochemistry of elemental polymerization steps, response kinetics, and the polymerization mechanism. The publication comprises an introductory bankruptcy for researchers who're getting into the sphere of polymerization catalysis. It describes the elemental rules of polymerization reactions with transition-metal catalysts and the categories of commercially synthetic polyolefins and copolymers

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Additional info for Alkene Polymerization Reactions with Transition Metal Catalysts

Sample text

6. Ethylene polymers and copolymers. Propylene polymers and copolymers. Ethylene/propylene elastomers and synthetic rubbers. Polymers and copolymers of higher 1-alkenes. Polymers and copolymers of cycloalkenes and cyclodienes. Crystalline syndiotactic polystyrene. Polyolefin resins are produced worldwide in a very large volume, B120 Â 106 metric tons/year in 2006, which corresponds to over 50% of the total production of all plastic materials. Ethylene polymers and copolymers account for 60–65% of the Transition Metal Catalysts and Catalytic Polymerization Reactions 29 total polyolefin production and propylene polymers for B35%; other types of polyolefin resins are manufactured in much lower volumes.

The average polymerization degree of a polymer produced in such experiments after a reaction time t is mn ¼ kp Á CM Á t. The molecular weight distribution of these polymers is described by the Poisson distribution function. 6) The mw/mn ratio corresponding to this distribution function is equal to 1+1/mn, and for any polymer of a sufficiently high molecular weight, mw/mnE1. If the chain initiation reaction in these reactions is relatively slow, the molecular weight distribution broadens because different macromolecules begin growing after different time delays with respect to the start of the polymerization reaction.

3. 1. 2. 4. 1. 2. 5. 1. 2. 3. 4. Compositional distribution of copolymers produced with multi-center catalysts 36 37 37 40 43 45 46 47 48 63 63 64 65 66 74 76 79 It can be stated with confidence that the overwhelming majority of solid and supported transition metal catalysts used for alkene polymerization, as well as many soluble catalysts, contain several types of active centers. The level of this confidence 35 36 Alkene Polymerization Reactions with Transition Metal Catalysts becomes clear if one compares alkene polymerization catalysts with heterogeneous catalysts used for other transformations of organic compounds.

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Alkene Polymerization Reactions with Transition Metal Catalysts by Yury Kissin

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