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The photoelectric effect is not the only interaction of x-rays with matter. Another important interaction is the elastic scattering of x-rays due to electrons, which is the origin of x-ray diffraction experiments. Elastic scattering is also known as Thomson scattering. indd 25 1/14/2008 8:06:38 PM 26 Core Level Spectroscopy of Solids with an x-ray and the diffracted x-rays are measured. The diffraction angle can be correlated with the interatomic distances using Bragg’s law. With respect to spectroscopy, it is important to note that the amount of x-rays involved in x-ray diffraction is almost constant with respect to the photon energy.

The letter is preceded by the principal quantum number. In many spectroscopies, one uses a third symbol to indicate the total angular momentum J of the core hole. The total angular momentum is given by l + s or l − s (in units of ¯h). The coupling of the orbital and the spin angular momenta is given by the spin–orbit interaction, which is essentially a relativistic effect. The spin–orbit interaction is very large for core holes and in general two peaks or structures will be visible in the spectrum, separated by the core hole spin–orbit splitting.

The most essential physical pictures for various recent topics on RXES are given, such as the charge-transfer and dd excitations in TM compounds and RE systems, characteristic electronic excitations and their spatial dispersions in high Tc cuprates, an RXES technique to detect weak electric-quadrupole and nonlocal electric-dipole transitions in the XAS pre-edge region of various materials, the MCD in RXES of ferromagnetic systems and so on. indd 10 1/12/2008 4:07:29 PM 2 Fundamental Aspects of Core Level Spectroscopies In this chapter, we introduce some fundamental aspects of core level spectroscopies.

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4-1BB by Vinay D.S., Kwon B.S.

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